Course coordinator
In class or by email. Refer to the Help section of Blackboard.
1st and 2nd laws of thermodynamics for steady and unsteady systems. Exergy analysis. Equations of state. Gibbs free energy, fugacity and activity. Phase equilibria, electrochemical equilibria. Pure components and solutions. Chemical reaction equilibria.
The main ideas covered in this course are:
1. Energy is conserved (1st Law).ᅠ Keeping track of energy is critically important in many processes and we will apply this to a range of processes.ᅠ
2. Energy always spreads (2nd Law). This imposes limits on what can and cannot be done.ᅠ
3. Phase and chemical equilibrium, regardless of the number of components, phases or reactions, is attained when the free energy of a system is minimised. This point is critical in solving a large number of Chemical Engineering problems and to scoping potential chemical processes.
4. Reliable data and/or equations are required to utilise points 1, 2, and 3 ᅠabove. There is a large amount of data and a large number of property equations (e.g. the various equations of state). The emphasis will be on using the data and equations and critically analysing if the data and/or equations used are suitable for the process you want to investigate.
You will have touched on these points before. This course will help you look at a range of problems to which these principles apply. Naturally this cannot be exhaustive, as Chemical Thermodynamics applies to many areas of engineering and science, but is rather aimed at equipping you with the tools and confidence to tackle unfamiliar problems using these principles.
This course expands upon concepts and knowledge from first year thermodynamics (ENGG1500) and ᅠfirst year ᅠchemistry (CHEM1100). Concepts such as enthalpy, entropy, heat capacity, the ideal gas law and the 1st and 2nd laws of thermodynamics, heats of reaction, and phase equilibrium should already be familiar to students.ᅠ Mathematics to a first year engineering level is required for ᅠthe manipulation of thermodynamic functions (e.g. derivatives, partial derivatives and integration).
You'll need to complete the following courses before enrolling in this one:
ENGG1500. CHEE2001 to be completed prior to or concurrently with this course.
You'll need to complete the following courses at the same time:
CHEE2001
You can't enrol in this course if you've already completed the following:
CHEE3003
In class or by email. Refer to the Help section of Blackboard.
The timetable for this course is available on the UQ Public Timetable.
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The aim of this course is to integrate concepts from chemistry and thermodynamics and extend them so students can apply them to realistic, as opposed to idealised, processes. With an understanding of these concepts, students will be able to critically analyse, formulate and solve diverse problems relating to energy and equilibrium.
The main ideas covered in this course are:
1. Energy is conserved (1st Law). Keeping track of energy is critically important in many processes and we will apply this to a range of processes.ᅠ
2. Energy always spreads (2nd Law). This imposes limits on what can and cannot be done.ᅠ
3. Phase and chemical equilibrium, regardless of the number of components, phases or reactions, is attained when the free energy of a system is minimised. This point is critical in solving a large number of Chemical Engineering problems and to scoping potential chemical processes.
4.ᅠReliable data and/or equations are required to utilise points 1, 2, and 3 above. There is a large amount of data and a large number of property equations (e.g. the various equations of state). The emphasis will be on using the data and equations and critically analysing if the data and/or equations used are suitable for the process you want to investigate.
You will have touched on these points before. This course will help you look at a range of problems to which these principles apply. Naturally this cannot be exhaustive, as Chemical Thermodynamics applies to many areas of engineering and science, but is rather aimed at equipping you with the tools and confidence to tackle unfamiliar problems using these principles.
After successfully completing this course you should be able to:
LO1.
Identify and explain the underlying thermodynamic principles of real processes: the first law, second law, and free energy minimisation.
LO2.
Source, and use, a wide range of thermodynamic data and charts.
LO3.
Explain the basis of ideal and non-ideal models for fluid and solution thermodynamic properties and apply them to process calculations.
LO4.
Identify and solve complex thermodynamic problems involving mass and energy balances, phase, and reaction equilibria.
LO5.
Use Matlab, Excel, and specialist thermodynamic software to perform complex thermodynamic calculations.
| Category | Assessment task | Weight | Due date |
|---|---|---|---|
| Tutorial/ Problem Set |
Problem Sets
|
26% Problem Set (Hurdle) |
Every second Monday at 4pm Weeks 3, 5, 6, 7, 9, 13, week 11 Tue 2pm. |
| Examination |
Exam – In-Semester Outside Scheduled Class
|
20% In-Semester Examination |
9/09/2024
18:00-20:00 |
| Practical/ Demonstration | Practical Phase Diagram | 4% |
18/09/2024 - 20/09/2024
Attend your signed-on session. |
| Examination |
Exam – during Exam Period (Central)
|
50% Final Examination (Hurdle) |
End of Semester Exam Period 2/11/2024 - 16/11/2024 |
A hurdle is an assessment requirement that must be satisfied in order to receive a specific grade for the course. Check the assessment details for more information about hurdle requirements.
Every second Monday at 4pm Weeks 3, 5, 6, 7, 9, 13, week 11 Tue 2pm.
Weekly problem sets will be worked on through the semester and submitted every second week.
They can be completed in self-formed pairs. No peer assessment will be applied. It is expected pairs will make an equal contribution. If your partner is not pulling their weight, form another pair! If this causes issues, discuss with coordinator. Individual submissions are allowed if you want or cannot find a partner that week.
The practice of the ICT - Python skills (Computer Exercise) class will be marked as one of problem sets.
The problem sets are evenly weighted. Your best 11 of 13 weekly problem sets (incl. ICT practice) will count towards determining your average mark for the problem sets.
The due dates for problem sets are every second Mon 4pm weeks 3, 5, 6, 7, 9, 13, week 11 Tue 2pm.
This assessment task evaluates students' abilities, skills and knowledge without the aid of generative Artificial Intelligence (AI) or Machine Translation (MT). Students are advised that the use of AI or MT technologies to develop responses is strictly prohibited and may constitute student misconduct under the Student Code of Conduct.
Submit online through Blackboard.
You may be able to apply for an extension.
Assessments must be submitted on or before the due date. Late submissions of assessment items will only be accepted if approval for late submission has been obtained prior to the due date.
Penalties Apply for Late Submission
Refer PPL Assessment Procedure Section 3 Part C (48)
Problem sets
Max Extension Period
24 hrs
Late Penalty (Submitted after due date without an approved extension)
100% Late penalty
Rationale
This policy is so we can return graded problem sets within days of submission and make solutions available so you get frequent feedback throughout the semester.
How assessment will be modified for a student with a valid reason for an extension longer than the Maximum Extension Period but less than or equal to 4 weeks
An approved extension for a problem set will result in an exemption (not an extension) and a reduction in your "best of" count for your problem sets.
9/09/2024
18:00-20:00
Closed book invigilated In-Semester Exam will cover materials of weeks 1 to 6. This exam may cover any material covered in those weeks except for calculations using Python/Excel/Factsage which are not part of the exam.
This assessment task evaluates students' abilities, skills and knowledge without the aid of generative Artificial Intelligence (AI) or Machine Translation (MT). Students are advised that the use of AI or MT technologies to develop responses is strictly prohibited and may constitute student misconduct under the Student Code of Conduct.
| Planning time | 10 minutes |
|---|---|
| Duration | 90 minutes |
| Calculator options | (In person) Casio FX82 series or UQ approved , labelled calculator only |
| Open/closed book | Closed Book examination - no written materials permitted |
| Exam platform | Paper based |
| Invigilation | Invigilated in person |
You may be able to defer this exam.
18/09/2024 - 20/09/2024
Attend your signed-on session.
Lab session where students work in groups to construct a ternary phase diagram for a liquid-liquid equlibrium system from experimental observation.
This assessment task evaluates students' abilities, skills and knowledge without the aid of generative Artificial Intelligence (AI) or Machine Translation (MT). Students are advised that the use of AI or MT technologies to develop responses is strictly prohibited and may constitute student misconduct under the Student Code of Conduct.
Lab sessions 46-542 Wet Lab.
18/9 Wed - PRA1 - 01 8am-10am; PRA 1 - 02 12pm-2pm; PRA 1 - 03 2pm-4pm; PRA 1 - 04 4pm-6pm;
19/9 Thu - PRA 1 - 05 12pm-2pm; PRA 1 - 06 2pm-4pm; PRA 1 - 07 4pm-6pm;
20/9 Fri - PRA 1 - 08 8am-10am; PRA 1 - 09 10am-12pm; PRA 1 -10 12pm-2pm;
Calculations and diagram submitted at the end of class (one set per group).
You may be able to apply for an extension.
The maximum extension allowed is 28 days. Extensions are given in multiples of 24 hours.
Assessments must be submitted on or before the due date. Late submissions of assessment items will only be accepted if approval for late submission has been obtained prior to the due date.
Penalties Apply for Late Submission
Refer PPL Assessment Procedure Section 3 Part C (48)
End of Semester Exam Period
2/11/2024 - 16/11/2024
Exam is closed book. Material from all weeks will be covered.
Students will be provided with a copy of the equation and data booklet.
This assessment task evaluates students' abilities, skills and knowledge without the aid of generative Artificial Intelligence (AI) or Machine Translation (MT). Students are advised that the use of AI or MT technologies to develop responses is strictly prohibited and may constitute student misconduct under the Student Code of Conduct.
| Planning time | 10 minutes |
|---|---|
| Duration | 180 minutes |
| Calculator options | (In person) Casio FX82 series or UQ approved , labelled calculator only |
| Open/closed book | Closed Book examination - no written materials permitted |
| Exam platform | Paper based |
| Invigilation | Invigilated in person |
You may be able to defer this exam.
Full criteria for each grade is available in the Assessment Procedure.
| Grade | Description |
|---|---|
| 1 (Low Fail) |
Absence of evidence of achievement of course learning outcomes. Course grade description: Typically 0 - 19.9% overall Fail: Essentially no evidence of effort or understanding. |
| 2 (Fail) |
Minimal evidence of achievement of course learning outcomes. Course grade description: Typically 20 - 44.9% overall OR with >=45% overall with with < 35% in problem sets and < 20% of the final examination assessment Fail: Demonstrates little understanding of the key concepts of the course. Will often start solutions on the wrong track and/or using methods/ calculations/ assumptions that contradict each other. May also fail to identify obvious sign and magnitude errors in erroneous calculations. |
| 3 (Marginal Fail) |
Demonstrated evidence of developing achievement of course learning outcomes Course grade description: Typically 45 - 49.9% overall with >= 35 % in problem sets and >= 25% examination assessment OR with >=50% overall with < 45% in problem sets and < 40% of the final examination assessment Fail: Demonstrates a poor understanding of some key concepts. Starts some solutions on the wrong track and/or using methods/calculations/assumptions that contradict each other. May also fail to identify obvious sign and magnitude errors. |
| 4 (Pass) |
Demonstrated evidence of functional achievement of course learning outcomes. Course grade description: Typically >= 50% overall with >= 45 % in problem sets and >= 40% of the final examination assessment Pass: Demonstrates a functional understanding of all concepts. Able to use these concepts to solve straight forward problems. Can start most complex problems with the correct concept and assumptions, but may not be able to complete the majority of these problems. Some contradictions are evident but should not be common. Able to identify most magnitude and sign errors. |
| 5 (Credit) |
Demonstrated evidence of proficient achievement of course learning outcomes. Course grade description: Typically >= 65% overall with >= 60% in problem sets and >= 55% of the final examination assessment Credit: Demonstrates a good understanding of all concepts in the course with perhaps a very good understanding of some. Simple problems are (essentially) correctly solved with more complex problems solved (or more progress in these problems) than for a 4 but with some significant errors still. Essentially no contradictions in concepts/ calculations/ assumptions are evident. Able to identify essentially all magnitude and sign errors in erroneous calculations (i.e. unrealistic solutions). |
| 6 (Distinction) |
Demonstrated evidence of advanced achievement of course learning outcomes. Course grade description: Typically >= 75% overall with >= 70% in problem sets and >= 65% of the final examination assessment Distinction: Demonstrates a very good understanding of concepts in the course that is unwavering when faced with unfamiliar problems. Simple problems are (essentially) correctly solved with most complex problems solved or with small errors. Errors (or incomplete solutions) are due to lack of attention to detail, not accounting for a subtlety of a problem or not being able to integrate several concepts in the one problem. Essentially no contradictions in concepts/ calculations/ assumptions are evident. Able to identify essentially all magnitude and sign errors in erroneous calculations (i.e. unrealistic solutions). |
| 7 (High Distinction) |
Demonstrated evidence of exceptional achievement of course learning outcomes. Course grade description: Typically >= 85% overall with >= 80% in problem sets and >= 75% of the final examination assessment High Distinction: Demonstrates a deep and robust understanding of all concepts in the course and an ability to transfer and use these concepts in a variety of contexts. Simple and complex problems are solved with the correct concepts/ calculations/ assumptions with only minor errors. Able to identify essentially all magnitude and sign errors in erroneous calculations (i.e. unrealistic solutions). |
The assessment is split into two parts: problem setsᅠ and examination assessment.
There are % requirements in both problem set ᅠand examination ᅠassessment for each grade band. ᅠ
The examination ᅠassessment % is calculated based on the weighted average of all examination ᅠassessment.
Supplementary assessment is available for this course.
Marks for a piece of assessment can only be changed within 4 weeks of assessment being returned to students (as opposed to when you check your assessment). Marks will not be changed after 4 weeks has elapsed. It is your responsibility to check that your mark on Grade Centre in Blackboard is correct.
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You'll need the following resources to successfully complete the course. We've indicated below if you need a personal copy of the reading materials or your own item.
Find the required and recommended resources for this course on the UQ Library website.
Course Blackboard site: https://learn.uq.edu.au. The Blackboard site will contain a variety of information related to the course including lecture and assessment material. Information will be sent to students through Blackboard.
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The learning activities for this course are outlined below. Learn more about the learning outcomes that apply to this course.
Filter activity type by
| Learning period | Activity type | Topic |
|---|---|---|
Multiple weeks |
Lecture |
Online lectures and readings Students are required to review the week's material before and complete the related online quizzes before the Workshop. |
Workshop |
Workshop (WKS) Active learning workshop targeting key concepts and skills for the week. This will help address common misconceptions and give you a head start for the Problem Sets that week. A combination of concept and clicker questions will be used. |
|
Problem-based learning |
Problem Based Learning (PBL) Class where students work on problem sets. This is a classroom learning environment where students get to ask questions related to how they are going. It is highly recommended that problem sets are started BEFORE the PBL. You will get a lot more out of the PBL if you do this and you will finish problem sets faster. |
|
Information technology session |
ICT - Python skills This will cover the functions and capabilities of Python that you will be required to use to solve some problems in this course. Learning outcomes: L05 |
|
Practical |
Practical Practical based on key concepts of the course Learning outcomes: L02, L03, L04 |
University policies and procedures apply to all aspects of student life. As a UQ student, you must comply with University-wide and program-specific requirements, including the:
Learn more about UQ policies on my.UQ and the Policy and Procedure Library.
Your school has additional guidelines you'll need to follow for this course:
Safety Induction for Practicals
Anyone undertaking courses with a practical component must complete the UQ Undergraduate Student Laboratory Safety Induction and pass the associated assessment.
Specific instructions, usage guidelines and rules for each of the undergraduate laboratories will be delivered as part of each course.
In some cases, students may be required to attend a specific face-to-face laboratory induction/training session.